Using MODIS image, we analyzed the relationship between surface albedo and underlying surface in Liaoning Province. In this paper, we not only compared the magnitude of albedos of different surface coverage types in Liaoning, we also analyzed the relation between MODIS Surface Albedo of various surface coverage types and NDVI. It worked out that the sequence of surface albedos in different kinds of areas are shown in the following: grassland > urban area > cropland > wetlands > water. The surface albedos of water, wetland, unban area and cropland are linearly correlation with NDVI, and the surface albedos of grassland and woodland are negatively linearly correlation with NDVI.